Chemical Heterogeneity across Cloud Droplet Size Spectra in Continental and Marine Air Masses

2000 ◽  
Vol 39 (6) ◽  
pp. 887-903 ◽  
Author(s):  
Surabi Menon ◽  
V. K. Saxena ◽  
B. D. Logie
Keyword(s):  
Droplet Size ◽  
Cloud Droplet ◽  
Chemical Heterogeneity ◽  
Size Spectra ◽  
Air Masses ◽  
Marine Air

scholarly journals Evaluating the capabilities and uncertainties of droplet measurements for the fog droplet spectrometer (FM-100)

2012 ◽  
Vol 5 (9) ◽  
pp. 2237-2260 ◽  
Author(s):  
J. K. Spiegel ◽  
P. Zieger ◽  
N. Bukowiecki ◽  
E. Hammer ◽  
E. Weingartner ◽  
...  
Keyword(s):  
Size Distribution ◽  
Droplet Size ◽  
Cloud Droplet ◽  
Droplet Size Distribution ◽  
Stochastic Approach ◽  
Mie Scattering ◽  
Size Distributions ◽  
Literature Study ◽  
Size Spectra ◽  
Wind Speeds

Abstract. Droplet size spectra measurements are crucial to obtain a quantitative microphysical description of clouds and fog. However, cloud droplet size measurements are subject to various uncertainties. This work focuses on the error analysis of two key measurement uncertainties arising during cloud droplet size measurements with a conventional droplet size spectrometer (FM-100): first, we addressed the precision with which droplets can be sized with the FM-100 on the basis of the Mie theory. We deduced error assumptions and proposed a new method on how to correct measured size distributions for these errors by redistributing the measured droplet size distribution using a stochastic approach. Second, based on a literature study, we summarized corrections for particle losses during sampling with the FM-100. We applied both corrections to cloud droplet size spectra measured at the high alpine site Jungfraujoch for a temperature range from 0 °C to 11 °C. We showed that Mie scattering led to spikes in the droplet size distributions using the default sizing procedure, while the new stochastic approach reproduced the ambient size distribution adequately. A detailed analysis of the FM-100 sampling efficiency revealed that particle losses were typically below 10% for droplet diameters up to 10 μm. For larger droplets, particle losses can increase up to 90% for the largest droplets of 50 μm at ambient wind speeds below 4.4 m s−1 and even to >90% for larger angles between the instrument orientation and the wind vector (sampling angle) at higher wind speeds. Comparisons of the FM-100 to other reference instruments revealed that the total liquid water content (LWC) measured by the FM-100 was more sensitive to particle losses than to re-sizing based on Mie scattering, while the total number concentration was only marginally influenced by particle losses. Consequently, for further LWC measurements with the FM-100 we strongly recommend to consider (1) the error arising due to Mie scattering, and (2) the particle losses, especially for larger droplets depending on the set-up and wind conditions.

DROPLET FEEDBACK ON VAPOR IN A WARM CLOUD

2009 ◽  
Vol 23 (28n29) ◽  
pp. 5434-5443 ◽  
Author(s):  
ANTONIO CELANI ◽  
ANDREA MAZZINO ◽  
MARCO TIZZI
Keyword(s):  
Numerical Simulations ◽  
Droplet Size ◽  
Cloud Droplet ◽  
Direct Numerical Simulations ◽  
Cloud Droplets ◽  
Size Spectra ◽  
New Model ◽  
Warm Cloud ◽  
Local Reduction ◽  
The One

A new model to study the effect of turbulence on the cloud droplets in the condensation phase is proposed and its behavior investigated by direct numerical simulations. The model is a generalization of the one by Celani, Mazzino, Tizzi, New J. Phys.10, 075021 (2008), where the droplet feedback on vapor is now explicitly taken into account. Physically, it amounts to considering the fact that when a cloud droplet increases its size, vapor is subtracted from the ambient with the net result of a local reduction in the supersaturation field. It is shown how this effect plays to reduce the broadening of droplet size spectra in the condensation stage and thus to produce results in closer agreement with observations.

scholarly journals Evaluating the capabilities and uncertainties of droplet measurements for the fog droplet spectrometer (FM-100)

2012 ◽  
Vol 5 (3) ◽  
pp. 3333-3393 ◽  
Author(s):  
J. K. Spiegel ◽  
P. Zieger ◽  
N. Bukowiecki ◽  
E. Hammer ◽  
E. Weingartner ◽  
...  
Keyword(s):  
Size Distribution ◽  
Droplet Size ◽  
Cloud Droplet ◽  
Droplet Size Distribution ◽  
Stochastic Approach ◽  
Liquid Water Content ◽  
Mie Scattering ◽  
Size Distributions ◽  
Literature Study ◽  
Size Spectra

Abstract. Droplet size spectra measurements are crucial to obtain a quantitative microphysical description of clouds and fog. However, cloud droplet size measurements are subject to various uncertainties. This work focuses on the evaluation of two key measurement uncertainties arising during cloud droplet size measurements with a conventional droplet size spectrometer (FM-100): first, we addressed the precision with which droplets can be sized with the FM-100 on the basis of Mie theory. We deduced error assumptions and proposed how to correct measured size distributions for these errors by redistributing the measured droplet size distribution using a stochastic approach. Second, based on a literature study, we derived corrections for particle losses during sampling with the FM-100. We applied both corrections to cloud droplet size spectra measured at the high alpine site Jungfraujoch for a temperature range from 0 °C to 11 °C. We show that Mie scattering led to spikes in the droplet size distributions using the default sizing procedure, while the stochastic approach reproduced the ambient size distribution adequately. A detailed analysis of the FM-100 sampling efficiency revealed that particle losses were typically below 10% for droplet diameters up to 10 μm. For larger droplets, particle losses can increase up to 90% for the largest droplets of 50 μm at ambient windspeeds below 4.4 m s−1 and even to >90% for larger angles between the instrument orientation and the wind vector (sampling angle) at higher wind speeds. Comparisons of the FM-100 to other reference instruments revealed that the total liquid water content (LWC) measured by the FM-100 was more sensitive to particle losses than to re-sizing based on Mie scattering, while the total number concentration was only marginally influenced by particle losses. As a consequence, for further LWC measurements with the FM-100 we strongly recommend to consider (1) the error arising due to Mie scattering, and (2) the particle losses, especially for larger droplets depending on the set-up and wind conditions.

scholarly journals Secondary new particle formation in Northern Finland Pallas site between the years 2000 and 2010

2011 ◽  
Vol 11 (24) ◽  
pp. 12959-12972 ◽  
Author(s):  
E. Asmi ◽  
N. Kivekäs ◽  
V.-M. Kerminen ◽  
M. Komppula ◽  
A.-P. Hyvärinen ◽  
...  
Keyword(s):  
Growth Rates ◽  
Cloud Condensation Nuclei ◽  
Cloud Droplet ◽  
Detailed Examination ◽  
Particle Formation ◽  
New Particle Formation ◽  
Air Masses ◽  
Event Frequency ◽  
Marine Air

Abstract. Secondary new particle formation affects atmospheric aerosol and cloud droplet numbers and thereby, the aerosol effects on climate. In this paper, the frequency of nucleation events and the associated particle formation and growth rates, along with their seasonal variation, was analysed based on over ten years of aerosol measurements conducted at the Pallas GAW station in northern Finland. The long-term measurements also allowed a detailed examination of factors possibly favouring or suppressing particle formation. Effects of meteorological parameters and air mass properties as well as vapour sources and sinks for particle formation frequency and event parameters were inspected. In addition, the potential of secondary particle formation to increase the concentration of cloud condensation nuclei (CCN) sized particles was examined. Findings from these long-term measurements confirmed previous observations: event frequency peaked in spring and the highest growth rates were observed in summer, affiliated with increased biogenic activity. Events were almost exclusively observed in marine air masses on sunny cloud-free days. A low vapour sink by the background particle population as well as an elevated sulphuric acid concentration were found to favour particle formation. These were also conditions taking place most likely in marine air masses. Inter-annual trend showed a minimum in event frequency in 2003, when also the smallest annual median of growth rate was observed. This gives further evidence of the importance and sensitivity of particle formation for the condensing vapour concentrations at Pallas site. The particle formation was observed to increase CCN80 (>80 nm particle number) concentrations especially in summer and autumn seasons when the growth rates were the highest. When the growing mode exceeded the selected 80 nm limit, on average in those cases, 211 ± 114% increase of CCN80 concentrations was observed.

scholarly journals Measurements of the relation between aerosol properties and microphysics and chemistry of low level liquid water clouds in Northern Finland

2008 ◽  
Vol 8 (23) ◽  
pp. 6925-6938 ◽  
Author(s):  
H. Lihavainen ◽  
V.-M. Kerminen ◽  
M. Komppula ◽  
A.-P. Hyvärinen ◽  
J. Laakia ◽  
...  
Keyword(s):  
Chemical Properties ◽  
Cloud Droplet ◽  
Simple Relation ◽  
Number Concentration ◽  
Cloud Droplets ◽  
Air Masses ◽  
Boundary Layer Clouds ◽  
Marine Air ◽  
Physical And Chemical ◽  
Aerosol Properties

Abstract. Physical and chemical properties of boundary layer clouds, together with relevant aerosol properties, were investigated during the first Pallas Cloud Experiment (First Pace) conducted in northern Finland between 20 October and 9 November 2004. Two stations located 6 km apart from each other at different altitudes were employed in measurements. The low-altitude station was always below the cloud layer, whereas the high-altitude station was inside clouds about 75% of the time during the campaign. Direct measurements of cloud droplet populations showed that our earlier approach of determining cloud droplet residual particle size distributions and corresponding activated fractions using continuous aerosol number size distribution measurements at the two stations is valid, as long as the cloud events are carefully screened to exclude precipitating clouds and to make sure the same air mass has been measured at both stations. We observed that a non-negligible fraction of cloud droplets originated from Aitken mode particles even at moderately-polluted air masses. We found clear evidence on first indirect aerosol effect on clouds but demonstrated also that no simple relation between the cloud droplet number concentration and aerosol particle number concentration exists for this type of clouds. The chemical composition of aerosol particles was dominated by particulate organic matter (POM) and sulphate in continental air masses and POM, sodium and chlorine in marine air masses. The inorganic composition of cloud water behaved similarly to that of the aerosol phase and was not influenced by inorganic trace gases.

scholarly journals Aerosol cloud activation in summer and winter at puy-de-Dôme high altitude site in France

2012 ◽  
Vol 12 (9) ◽  
pp. 23039-23091
Author(s):  
E. Asmi ◽  
E. Freney ◽  
M. Hervo ◽  
D. Picard ◽  
C. Rose ◽  
...  
Keyword(s):  
High Altitude ◽  
Volume Fraction ◽  
Cloud Condensation Nuclei ◽  
Cloud Droplet ◽  
Mass Composition ◽  
Size Distributions ◽  
Air Masses ◽  
Size Dependent ◽  
Cloud Properties ◽  
Marine Air

Abstract. Cloud condensation nuclei (CCN) size distributions and numbers were measured for the first time at Puy-de-Dôme high altitude (1465 m a.s.l) site in Central France. Majority of the measurements were done at constant supersaturation (SS) of 0.24%, which was also deduced to be representative of the typical in-cloud SS at the site. CCN numbers during summer ranged from about 200 up to 2000 cm−3 and during winter from 50 up to 3000 cm−3. Variability of CCN number was explained by both particle chemistry and size distribution variability. The higher CCN concentrations were measured in continental, in contrast to marine, air masses. Aerosol CCN activity was described with a single hygroscopicity parameter κ. Range of this parameter was 0.29 ± 0.13 in summer and 0.43 ± 0.19 in winter. When calculated using SS of 0.51% during summer, κ of 0.22 ± 0.07 was obtained. The decrease with increasing SS is likely explained by the particle size dependent chemistry with smaller particles containing higher amounts of freshly emitted organic species. Higher κ values during winter were for the most part explained by the observed aged organics (analysed from organic m/z 44 ratio) rather than from aerosol organic to inorganic volume fraction. The obtained κ values also fit well within the range of previously proposed global continental κ of 0.27 ± 0.21. During winter, the smallest κ values and the highest organic fractions were measured in marine air masses. CCN closure using bulk AMS chemistry led to positive bias of 5% and 2% in winter and summer, respectively. This is suspected to stem from size dependent aerosol organic fraction, which is underestimated by using AMS bulk mass composition. Finally, the results were combined with size distributions measured from interstitial and whole air inlets to obtain activated droplet size distributions. Cloud droplet number concentrations were shown to increase with accumulation mode particle number, while the real in-cloud SS correspondingly decreased. These results provide evidence on the effects of aerosol particles on maximum cloud supersaturations. Further work with detailed characterisation of cloud properties is proposed in order to provide more quantitative estimates on aerosol effects on clouds.

scholarly journals Aerosol cloud activation in summer and winter at puy-de-Dôme high altitude site in France

2012 ◽  
Vol 12 (23) ◽  
pp. 11589-11607 ◽  
Author(s):  
E. Asmi ◽  
E. Freney ◽  
M. Hervo ◽  
D. Picard ◽  
C. Rose ◽  
...  
Keyword(s):  
High Altitude ◽  
Volume Fraction ◽  
Cloud Condensation Nuclei ◽  
Cloud Droplet ◽  
Mass Composition ◽  
Size Distributions ◽  
Air Masses ◽  
Size Dependent ◽  
Cloud Properties ◽  
Marine Air

Abstract. Cloud condensation nuclei (CCN) size distributions and numbers were measured for the first time at Puy-de-Dôme high altitude (1465 m a.s.l) site in Central France. Majority of the measurements were done at constant supersaturation (SS) of 0.24%, which was also deduced to be representative of the typical in-cloud SS at the site. CCN numbers during summer ranged from about 200 up to 2000 cm−3 and during winter from 50 up to 3000 cm−3. Variability of CCN number was explained by both particle chemistry and size distribution variability. The higher CCN concentrations were measured in continental, in contrast to marine, air masses. Aerosol CCN activity was described with a single hygroscopicity parameter κ. Range of this parameter was 0.29 ± 0.13 in summer and 0.43 ± 0.19 in winter. When calculated using SS of 0.51% during summer, κ of 0.22 ± 0.07 was obtained. The decrease with increasing SS is likely explained by the particle size dependent chemistry with smaller particles containing higher amounts of freshly emitted organic species. Higher κ values during winter were for the most part explained by the observed aged organics (analysed from organic m/z 44 ratio) rather than from aerosol organic to inorganic volume fraction. The obtained κ values also fit well within the range of previously proposed global continental κ of 0.27 ± 0.21. During winter, the smallest κ values and the highest organic fractions were measured in marine air masses. CCN closure using bulk AMS chemistry led to positive bias of 5% and 2% in winter and summer, respectively. This is suspected to stem from size dependent aerosol organic fraction, which is underestimated by using AMS bulk mass composition. Finally, the results were combined with size distributions measured from interstitial and whole air inlets to obtain activated droplet size distributions. Cloud droplet number concentrations were shown to increase with accumulation mode particle number, while the real in-cloud SS correspondingly decreased. These results provide evidence on the effects of aerosol particles on maximum cloud supersaturations. Further work with detailed characterisation of cloud properties is proposed in order to provide more quantitative estimates on aerosol effects on clouds.

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